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IC 9188 



Bureau of Mines Information Circular/1988 




Analyses of Natural Gases, 1987 



By B. J. Moore and Stella Sigler 



UNITED STATES DEPARTMENT OF THE INTERIOR 




• 9 

Information Circular 9188 X.e. 

Analyses of Natural Gases, 1987 

By B. J. Moore and Stella Sigler 



UNITED STATES DEPARTMENT OF THE INTERIOR 
Donald Paul Model, Secretary 

BUREAU OF MINES 
T S Ary, Director 



5inoL lei- 



Library of Congress Cataloging in Publication Data: 



Moore, B. J. (BiUy J.) 




Analyses of natural gases, 1987. 




(Information circular, 9188) 




Bibliography: p. 74 




Supt. of Docs, no.: 128.27:9188. 




1. Gas, Natural— United States— Analyses. 
ni. Series: Information circular (United States. 


I. Sigler, Stella. II. Title. 
Bureau of Mines); 9188. 


TN295.U4 [TP350] 622 s 


[668.7] 88-600364 



CONTENTS 

Page 

Abs t ract 1 

Introduction 2 

Geologic provinces of the United States 2 

Tables 8 

Previous publications in this series 74 

ILLUSTRATION 

1. Geologic provinces of the United States 3 

TABLES 

1. Samples from gas and oil wells in the United States 9 

2. Samples from pipelines in the United States 69 

3. Samples from gas and oil wells in foreign countries 72 



ANALYSES OF NATURAL GASES, 1987 

By B. J. Moore^ and Stella Sigler^ 



ABSTRACT 

This publication contains analyses and related source data for 191 
natural gas samples from 22 states and 1 foreign country. Of the total 
samples, 182 were collected during calendar year 1987. The remainder 
were collected earlier, but releases granting permission to publish were 
not received before 1987. All samples were obtained and analyzed as 
part of Bureau of Mines investigations of the occurrences of helium in 
natural gases of countries with free market economies. This survey has 
been conducted since 1917. The analyses published herein were made by 
mass spectrometer and chromatograph. 

^Petroleum engineer. 
2Helium resources survey clerk. 
Section of Helium Resources Evaluation, Branch of Helium Resources, Helium Field 
Operations, Bureau of Mines, Amarillo, TX. 



INTRODUCTION 



This Bureau of Mines publication con- 
tains analyses and related source data 
for 191 natural gas samples from 22 
states and 1 foreign country. Of these 
samples, 182 were collected during calen- 
dar year 1987; 9 samples were collected 
earlier, but releases granting permission 
to publish were not received before 1987. 
All samples were obtained and analyzed as 
part of Bureau of Mines investigations of 
the occurrences of helium in natural 
gases of countries with free market eco- 
nomies. This survey has been conducted 
since 1917. The analyses published here- 
in were made by the mass spectrometer and 
chroma tograph. 

The results of these investigations are 
published annually to make the informa- 
tion available to the petroleum industry 
and the general public. Thirty-two pub- 
lications have presented the results of 
14,738 gas analyses made prior to 1987. 
The first three bulletins (JL~3^)^ contain 
analyses and related source data on 5,218 
gas samples collected from 1917 through 
1960; these bulletins have been supple- 
mented annually by information circulars 
(_4-n_, ^9-24, 26-30, 32) containing 9,520 
analyses of samples collected since 
1960. 

I.- 1976, a compilation of the analyses 
made prior to 1975 was prepared by the 
Bureau of Mines and published by the 
National Technical Information Service of 
the- U.S. Department of Commerce (18). 
This compilation contains 10,562 analyses 



of gas samples from gas ana oil wells and 
natural gas pipelines in 37 States and 23 
foreign countries. In 1982, a compila- 
tion of analyses made prior to 1981 was 
published (25). The 1982 publication 
contains 12,554 analyses of gas samples 
from gas and oil wells and natural gas 
pipelines in 39 States and 24 foreign 
countries and includes the analyses from 
1976 publication. The latest of these 
compilations was published in 1987 and 
contains 14,242 analyses made prior to 
1986, including the analyses from the 
1976 and 1982 publications. The samples 
were taken from wells or pipelines in 40 
States and 24 foreign countries (31 ). 

In addition to being in the publica- 
tions, all analyses and related informa- 
tion published through 1987 are available 
on a magnetic tape file. The tape is 
available for $200 from the National 
Technical Information Service, Spring- 
field, VA 22161, telephone (703) 487- 
4650; orders should refer to Bureau of 
Mines tape PB 88-172325. 

The helium survey program is conducted 
by soliciting natural gas samples 
throughout the United States and other 
countries with free market economies. 
Without the assistance of the petroleum 
industry, State and Federal agencies, and 
many individuals engaged in oil and gas 
exploration and production, the helium 
survey in its present scope would not be 
possible. 



GEOLOGIC PROVINCES OF THE UNITED STATES 



The tables include geologic province 
codes so each sample source can be 
located within a specific geologic prov- 
ince as defined by the Committee on 
Statistics of Drilling of the American 
Association of Petroleum Geologists.^ 
These provinces, which are given in the 
following list and shown in figure 1, are 

■^Underlined numbers in parentheses re- 
fer to items in the list of previous 
publications at the end of this report. 

^Meyer, R. F. Geologic Provinces Code 
Map for Computer Use. AAPG Bull., v. 54, 
No. 7, July 1970, pp. 1301-1305. 



delineated by political boundaries for 
convenience and for accommodation of 
data processing equipment. Not all of 
the provinces shown are gas-producing 
areas, so many of the codes are not used 
in this publication. Since State or 
Federal ownership is not always known in 
offshore areas, only one code is used for 
each State. Owing to the lack of infor- 
mation on the location of wells in 
Alaska, only one code, 972, is used for 
all wells. 

The following list and figure 1 are 
taken from the article cited in footnote 
4. 




(U 
D 

0) 



<U 
U 

c 

> 

o 

Q. 
U 

_o 

O 

o 
O 



LU 
O 



Code Province 



100 


no 


120 


130 


140 


150 


160 


200 


210 


220 


230 


240 


250 


260 


300 


305 


310 


315 


320 


325 


330 


335 


340 


345 


350 


355 


360 


365 


370 


375 


380 


385 


390 


395 


400 


405 


410 


415 


420 


425 


430 


435 


440 


445 


450 


455 


460 


465 


470 


475 



New England Province 

Adirondack Uplift 

Atlantic Coast Basin 

South Georgia-North Florida Sedimentary Province 

South Florida Province 

Piedmont-Blue Ridge Province 

Appalachian Basin 

Warrior Basin 

Mid-Gulf Coast Basin 

Gulf Coast Basin 

Arkla Basin 

Desha Basin 

Upper Mississippi Embayment 

East Texas Basin 

Cincinnati Arch 

Michigan Basin 

Wisconsin Arch 

Illinois Basin 

Sioux Uplift 

Iowa Shelf 

Lincoln Anticline 

Forest City Basin 

Ozark Uplift 

Arkoma Basin 

South Oklahoma Folded Belt Province 

Chautauqua Platform 

Anadarko Basin 

Cherokee Basin 

Nemaha Anticline 

Sedgwick Basin 

Salina Basin 

Central Kansas Uplift 

Chadron Arch 

Williston Basin 

Ouachita Tectonic Belt Province 

Kerr Basin 

Llano Uplift 

St r awn Basin 

Fort Worth Syncline 

Bend Arch 

Permian Basin 

Palo Duro Basin 

Amarillo Arch 

Sierra Grande Uplift 

Las Animas Arch 

Las Vegas -Rat on Basin 

Estancia Basin 

Orogrande Basin 

Pedregosa Basin 

Basin-and-Range Province 



Code Province 

Sweetgrass Arch 

Montana Folded Belt Province 

Central Montana Uplift 

Powder River Basin 

Big Horn Basin 

Yellowstone Province 

Wind River Basin 

Green River Basin 

Denver Basin 

North Park Basin 

South Park Basin 

Eagle Basin 

San Luis Basin 

San Juan Mountain Province 

Uinta Uplift 

Uinta Basin 

San Juan Basin 

Paradox Basin 

Black Mesa Basin 

Plceance Basin 

Northern Cascade Range — Okanagan Province 

Eastern Columbia Basin 

Idaho Mountains Province 

Snake River Basin 

Southern Oregon Basin 

Great Basin Province 

Wasatch Uplift 

Plateau Sedimentary Province 

Mojave Basin 

Salton Basin 

Sierra Nevada Province 

Bellingham Basin 

Puget Sound Province 

Western Columbia Basin 

Klamath Mountains Province 

Eel River Basin 

Northern Coast Range Province 

Sacramento Basin 

Santa Cruz Basin 

Coastal Basins 

San Joaquin Basin 

Santa Maria Basin 

Ventura Basin 

Los Angeles Basin 

Capistrano Basin 

Heceta Island Area 
Keku Islands Area 
Gulf of Alaska Basin 
Copper River Basin 
Cook Inlet Basin 



500 


505 


510 


515 


520 


525 


530 


535 


540 


545 


550 


555 


560 


565 


570 


575 


580 


585 


590 


595 


600 


605 


610 


615 


620 


625 


630 


635 


640 


645 


650 


700 


705 


710 


715 


720 


725 


730 


735 


740 


745 


750 


755 


760 


765 


800 


805 


810 


815 


820 



Code Province 

830 Kandik Province 

835 Kobuk Province 

840 Koyukuk Province 

845 Bristol Bay Basin 

850 Bethel Basin 

855 Norton Basin 

860 Selawik Basin 

863 Yukon Flats Basin 

865 Lower Tanana Basin 

867 Middle Tanana Basin 

870 Upper Tanana Basin 

873 Galena Basin 

875 Innoko Basin 

877 Minchumina Basin 

880 Holitna Basin 

885 Arctic Foothills Province 

890 Arctic Slope Basin 

900 Maine Atlantic offshore — general 

901 Maine Atlantic offshore — State 

902 Maine Atlantic offshore — Federal 

903 New Hampshire Atlantic offshore — general 

904 New Hampshire Atlantic offshore — State 

905 New Hampshire Atlantic offshore — Federal 

906 Massachusetts Atlantic offshore — general 

907 Massachusetts Atlantic offshore — State 

908 Massachusetts Atlantic offshore — Federal 

909 Rhode Island Atlantic offshore — general 

910 Rhode Island Atlantic offshore — State 

911 Rhode Island Atlantic offshore — Federal 

912 Connecticut Atlantic offshore — general 

913 Connecticut Atlantic offshore — State 

914 Connecticut Atlantic offshore — Federal 

915 New York Atlantic offshore — general 

916 New York Atlantic offshore — State 

917 New York Atlantic offshore — Federal 

918 New Jersey Atlantic offshore — general 

919 New Jersey Atlantic offshore — State 

920 New Jersey Atlantic offshore — Federal 

921 Delaware Atlantic offshore — general 

922 Delaware Atlantic offshore — State 

923 Delaware Atlantic offshore — Federal 

924 Maryland Atlantic offshore — general 

925 Maryland Atlantic offshore — State 

926 Maryland Atlantic offshore — Federal 

927 Virginia Atlantic offshore — general 

928 Virginia Atlantic offshore — State 

929 Virginia Atlantic offshore — Federal 

930 North Carolina Atlantic offshore — general 

931 North Carolina Atlantic offshore — State 

932 North Carolina Atlantic offshore — Federal 

933 South Carolina Atlantic offshore — general 

934 South Carolina Atlantic offshore — State 



Code Province 

935 South Carolina Atlantic offshore — Federal 

936 Georgia Atlantic offshore — general 

937 Georgia Atlantic offshore — State 

938 Georgia Atlantic offshore — Federal 

939 Florida Atlantic offshore — general 

940 Florida Atlantic offshore — State 

941 Florida Atlantic offshore — Federal 

942 Florida Gulf of Mexico offshore — general 

943 Florida Gulf of Mexico offshore — State 

944 Florida Gulf of Mexico offshore — Federal 

945 Alabama Gulf of Mexico offshore — general 

946 Alabama Gulf of Mexico offshore — State 

947 Alabama Gulf of Mexico offshore — Federal 

948 Mississippi Gulf of Mexico offshore — general 

949 Mississippi Gulf of Mexico offshore — State 

950 Mississippi Gulf of Mexico offshore — Federal 

951 Louisiana Gulf of Mexico offshore — general 

952 Louisiana Gulf of Mexico offshore — State 

953 Louisiana Gulf of Mexico offshore — Federal 

954 Texas Gulf of Mexico offshore — general 

955 Texas Gulf of Mexico offshore — State 

956 Texas Gulf of Mexico offshore — Federal 

957 California Pacific offshore — general 

958 California Pacific offshore — State 

959 California Pacific offshore — Federal 

960 Oregon Pacific offshore — general 

961 Oregon Pacific offshore — State 

962 Oregon Pacific offshore — Federal 

963 Washington Pacific offshore — general 

964 Washington Pacific offshore — State 

965 Washington Pacific offshore — Federal 

972 Alaska Arctic offshore — general 

973 Alaska Arctic offshore — State 

974 Alaska Arctic offshore — Federal 

975 Alaska Bering Sea offshore — general 

976 Alaska Bering Sea offshore — State 

977 Alaska Bering Sea offshore — Federal 

978 Alaska Pacific offshore — general 

979 Alaska Pacific offshore — State 

980 Alaska Pacific offshore — Federal 

987 Minnesota Lake Superior offshore 

988 Wisconsin Lake Superior offshore 

989 Michigan Lake Superior offshore 

990 Indiana Lake Michigan offshore 

991 Illinois Lake Michigan offshore 

992 Wisconsin Lake Michigan offshore 

993 Michigan Lake Michigan offshore 

994 Michigan Lake Huron offshore 

995 Michigan Lake Erie offshore 

996 Ohio Lake Erie offshore 

997 Pennsylvania Lake Erie offshore 

998 New York Lake Erie offshore 

999 New York Lake Ontario offshore 



TABLES 

The following tables include the results of analyses and related source data from 
gas samples, which are divided into three groups as follows: 

Table 1. - Samples from gas and oil wells in the United States. 

Table 2. - Samples from pipelines in the United States. 

Table 3. - Samples from gas and oil wells in foreign countries. 

The following list indicates the sources of the samples listed in the tables: 



Source 



Number 

of 
samples 



Tables 



Source 



Number 

of 
samples 



Tables 



Alabama. . . . . 
Arkansas. . . • 
California. . 
Colorado. . . . 

Idaho 

Kansas 

Kentucky. . . . 
Louisiana. . . 
Michigan. . . . 
Mississippi. 
Montana. . . . . 
New Mexico. . 



4 

19 

1 

9 

2 

11 

1 

6 

5 

7 

1 

12 



New York 

North Dakota. . 

Ohio 

Oklahoma 

Pennsylvania. . 

Tennessee 

Texas 

Utah 

West Virginia. 
Wyoming 



4 
2 
1 

45 
3 
1 

38 
3 
6 
5 



> 2 
, 2 
. 2 



Canada. 



All components of the analyses in the tables are reported to the nearest 0.1%, except 
helium, which is reported to the nearest 0.01%. The word "Trace" is used to denote 
quantities of helium of less than 0.005% and quantities of other components of less 
than 0.05%. 



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74 



PREVIOUS PUBLICATIONS IN THIS SERIES 



1. Anderson, C. C. , and H. H. Hinson. 
Helium-Bearing Natural Gases of the 
United States. Analyses and Analytical 
Methods. BuMines B 486, 1951, 141 pp. 

2. Boone, W. J. , Jr. Helium-Bearing 
Natural Gases of the United States. 
Analyses and Analytical Methods. Supple- 
ment to Bulletin 486. BuMines B 576, 
1958, 117 pp. 

3. Munnerlyn, R. D. , and R. D. 
Miller. Helium-Bearing Natural Gases of 
the United States, Analyses. Second 
Supplement to Bulletin 486. BuMines 
B 617, 1963, 93 pp. 

4. Miller, R. D. , and G. P. Norrell. 
Analyses of Natural Gases of the United 
States, 1961. BuMines IC 8221, 1964, 
148 pp. 

5. . Analyses of 
of 



Natural Gases 
1962. BuMines 



Natural Gases 
1963. BuMines 



the United States, 
IC 8239, 1964, 120 pp. 

6. . Analyses of 

of the United States, 
IC 8241, 1965, 102 pp. 

7. Moore, B. J. , R. D. Miller, and 
R. D. Shrewsbury. Analyses of Natural 
Gases of the United States, 1964. Bu- 
Mines IC 8302, 1966, 144 pp. 

8. Moore, B. J. , and R. D. Shrews- 
bury. Analyses of Natural Gases of the 
United States, 1965. BuMines IC 8316, 
1966, 181 pp. 

9. . Analyses of Natural Gases, 

1966. BuMines IC 8356, 1967, 130 pp. 

10. __. Analyses of Natural Gases, 

1967. BuMines IC 8395, 1968, 187 pp. 

11. Cardwell, L. E. , and L. F. Benton. 
Analyses of Natural Gases, 1968. BuMines 
IC 8443, 1970, 169 pp. 

12. . Analyses of Natural Gases, 

1969. BuMines IC 8475, 1970, 134 pp. 

13. . Analyses of Natural Gases, 

1970. BuMines IC 8518, 1971, 130 pp. 

14. . Analyses of Natural Gases, 

1971. BuMines IC 8554, 1972, 163 pp. 



15. Cardwell, L. E. , and L. F. Benton. 
Analyses of Natural Gases, 1972. BuMines 
IC 8607, 1973, 104 pp. 

16. Moore, B. J. Analyses of Natural 
Gases, 1973. BuMines IC 8658, 1974, 
96 pp. 

17. 
1974. 

18. 
1917-74. 

19. 
1975. 

20. 
1976. 

21. 
1977. 

22. 
1978. 

23. 
1979. 

24. 
1980. 

25. 



. Analyses of Natural Gases, 

BuMines IC 8684, 1975, 122 pp. 

. Analyses of Natural Gases, 

NTIS PB 251-202, 1976, 889 pp. 

. Analyses of Natural Gases, 

BuMines IC 8717, 1976, 82 pp. 

. Analyses of Natural Gases, 

BuMines IC 8749, 1977, 94 pp. 

. Analyses of Natural Gases, 

BuMines IC 8780, 1978, 95 pp. 

. Analyses of Natural Gases, 

BuMines IC 8810, 1979, 113 pp. 

. Analyses of Natural Gases, 

BuMines IC 8833, 1980, 100 pp. 

. Analyses of Natural Gases, 

BuMines IC 8856, 1981, 236 pp. 
. Analyses of Natural Gases, 

1917-80. BuMines IC 8870, 1982, 1055 pp. 
26. Miller, R. D. , and F. R. Hertweck, 

Jr. Analyses of Natural Gases, 1981. 

BuMines IC 8890, 1982, 84 pp. 
27. 

1982. 
28. 

D. D. 

1983. 
29. 



. Analyses of Natural Gases, 

BuMines IC 8942, 1983, 100 pp. 

Hertweck, F. R. , Jr., and 
Fox. Analyses of Natural Gases, 

BuMines IC 8993, 1984, 127 pp. 

Moore, B. J. , and J. E. Hamak. 
Analyses of Natural Gases, 1984. BuMines 
IC 9046, 1985, 102 pp. 

30. Moore, B. J. , and S. Sigler. 
Analyses of Natural Gases, 1985. BuMines 
IC 9096, 1986, 182 pp. 

31. . Analyses of Natural Gases, 

1917-85. BuMines IC 9129, 1987, 1197 pp. 

32. . Analyses of Natural Gases, 

1986. BuMines IC 9167, 1988, 101 pp. 



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